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dc.contributor.authorPlajer, Alex J.
dc.contributor.authorGarcía Rodríguez, Raúl 
dc.contributor.authorRizzuto, Felix J.
dc.contributor.authorWright, Dominic Simon
dc.date.accessioned2018-12-11T09:20:02Z
dc.date.available2019-04-04T23:40:15Z
dc.date.issued2018
dc.identifier.citationChemistry A European Journal, 2018, Volume 24, Issue 8,Pages 2013-2019es
dc.identifier.issn0947-6539es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/33401
dc.descriptionProducción Científicaes
dc.description.abstractOxidation of the PIII dianion [S−P(μ‐NtBu)]22− (1) with elemental sulphur, selenium and tellurium gives the PV dianions [(S)(E)P(μ‐NtBu)]22− (E = S (6 a), Se (6 b), Te (6 c)). Although 6 c proves to be too unstable, the S,S‐dianion 6 a and ambidentate S,Se‐dianion 6 b are readily transferred intact to main group and transition metal elements, producing a range of new cage and coordination compounds. While their coordination characteristics are in many ways similar to closely‐related isoelectronic phosph(V)azane anions [(E)(RN=)P(μ‐NtBu)]22−, the sterically unhindered nature of 6 introduces an expanded range of coordination modes, that is, facial S,S‐ and Se,Se‐bonding as well as side‐on S,Se‐coordination. All of these bonding modes are observed for the amibidentate S,Se dianion 6 b.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationOxidación del dianiónes
dc.subject.classificationOxidation of the dianiones
dc.titleFlexible Bonding of the Phosph(V)azane Dianions [S(E)P(μ‐NtBu)]22−es
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doihttps://doi.org/10.1002/chem.201705413es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/chem.201705413es
dc.peerreviewedSIes
dc.description.embargo2019-04-04es
dc.description.projectMinisterio de Economía, Industria y Competitividad - Agencia Estatal de Investigación (AEI)es
dc.description.projectEuropean Social Fund (ESF)es
dc.description.projectRamon y Cajal contract (RG-R, RYC-2015 -19035 )es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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