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dc.contributor.authorDomínguez, Cristina
dc.contributor.authorHeinrich, Benoît
dc.contributor.authorDonnio, Bertrand
dc.contributor.authorCoco Cea, Silverio 
dc.contributor.authorEspinet Rubio, Pablo 
dc.date.accessioned2018-12-21T08:12:28Z
dc.date.available2018-12-21T08:12:28Z
dc.date.issued2013
dc.identifier.citationChemistry - A European Journal, 2013, Volume19, Issue19, Pages 5988-5995es
dc.identifier.issn0947-6539es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/33603
dc.descriptionProducción Científicaes
dc.description.abstractSupramolecular mono‐ and dinuclear liquid‐crystalline gold(I) aggregates have been synthesized by means of hydrogen bond interactions of 2,4,6‐triarylamino‐1,3,5‐triazine with thiolate moities of gold metalloacids [Au(PR3)(SC6H4COOH)] or [μ‐(binap){Au(SC6H4COOH)}2], in 1:1 and 2:1 molar ratio, respectively. All of the supramolecular aggregates display a stable columnar hexagonal mesophase (Colh) at room‐temperature. The supramolecular arrangement within the columns consists of the one‐dimensional stacking of triazine units, with the core of the attached metallic thioacid fragments acting as the fourth branch. The phosphine‐containing moieties of the metallic thioacid protrude out in the aliphatic continuum. These complexes do not show metallophilic interactions, but this strategy appears very promising for the future design of room‐temperature LC mesophases containing interacting metallic fragments.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationOroes
dc.subject.classificationEnlaces de hidrógenoes
dc.subject.classificationCristales líquidoses
dc.subject.classificationTriazinaes
dc.subject.classificationGoldes
dc.subject.classificationHydrogen bondinges
dc.subject.classificationLiquid crystalses
dc.subject.classificationTriazinees
dc.titleRoom‐Temperature Columnar Mesophases in Triazine–Gold Thiolate Metal–Organic Supramolecular Aggregateses
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doihttps://doi.org/10.1002/chem.201204256es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/chem.201204256es
dc.peerreviewedSIes
dc.description.projectMinisterio de Ciencia e Innovación (Proyect CTQ2011–25137)es
dc.description.projectJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA248 A11‐2)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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