• español
  • English
  • français
  • Deutsch
  • português (Brasil)
  • italiano
    • español
    • English
    • français
    • Deutsch
    • português (Brasil)
    • italiano
    • español
    • English
    • français
    • Deutsch
    • português (Brasil)
    • italiano
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of UVaDOCCommunitiesBy Issue DateAuthorsSubjectsTitles

    My Account

    Login

    Statistics

    View Usage Statistics

    Share

    View Item 
    •   UVaDOC Home
    • SCIENTIFIC PRODUCTION
    • Departamentos
    • Dpto. Química Física y Química Inorgánica
    • DEP63 - Artículos de revista
    • View Item
    •   UVaDOC Home
    • SCIENTIFIC PRODUCTION
    • Departamentos
    • Dpto. Química Física y Química Inorgánica
    • DEP63 - Artículos de revista
    • View Item
    • español
    • English
    • français
    • Deutsch
    • português (Brasil)
    • italiano

    Export

    RISMendeleyRefworksZotero
    • edm
    • marc
    • xoai
    • qdc
    • ore
    • ese
    • dim
    • uketd_dc
    • oai_dc
    • etdms
    • rdf
    • mods
    • mets
    • didl
    • premis

    Citas

    Academic Search

    Por favor, use este identificador para citar o enlazar este ítem:http://uvadoc.uva.es/handle/10324/38346

    Título
    [Cu(C6Cl2F2)(tht)]4: An Extremely Efficient Catalyst for the Aryl Scrambling between Palladium Complexes
    Autor
    Pérez Iglesias, Maríauntranslated
    Lozano Lavilla, Olmo
    Casares González, Juan Ángeluntranslated ORCID
    Año del Documento
    2019
    Documento Fuente
    Organometallics, 2019, 38, 739–742
    Abstract
    The copper compound [Cu(C6Cl2F3)(tht)]4 (1) (tht: tetrahydrothiophene) is an excellent catalyst for the trans-to-cis isomerization of complexes [PdAr2(tht)2](Ar: fluoroaryl) and also for the exchange of aryls between those palladium complexes. Herein, we also communicate the synthesis and characterization of 1 and some of its derivatives. The X-ray structure of 1 shows a linear chain of copper atoms, supported by fluoroaryl rings. The nuclear magnetic resonance 19F diffusion-ordered spectroscopy study indicates that this structure is preserved in solution, although it is in equilibrium with other species.
    ISSN
    0276-7333
    Revisión por pares
    SI
    DOI
    10.1021/acs.organomet.8b00885
    Idioma
    spa
    URI
    http://uvadoc.uva.es/handle/10324/38346
    Tipo de versión
    info:eu-repo/semantics/draft
    Derechos
    openAccess
    Collections
    • DEP63 - Artículos de revista [188]
    Show full item record
    Files in this item
    Nombre:
    text.pdf
    Tamaño:
    1.222Mb
    Formato:
    Adobe PDF
    Descripción:
    artículo
    Thumbnail
    FilesOpen

    Comentarios

    Universidad de Valladolid

    Powered by MIT's. DSpace software, Version 5.10