2024-03-28T09:31:55Zhttp://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/225102021-06-23T11:52:28Zcom_10324_1186com_10324_931com_10324_894col_10324_1404
2017-03-09T09:28:25Z
urn:hdl:10324/22510
Generation and structural characterization of aluminum cyanoacetylide
Cabezas, Carlos
Barrientos Benito, María Carmen
Largo Cabrerizo, Antonio
Guillemin, Jean-Claude
Cernicharo, José
Producción Científica
Combined spectroscopy measurements and theoretical calculations bring to light a first investigation of a metallic cyanoacetylide, AlC3N, using laser ablation molecular beam Fourier transform microwave spectroscopy. This molecule was synthesized in a supersonic expansion by the reaction of aluminum vapour with C3N, produced from solid aluminum rods and BrCCCN in a newly constructed ablation-heating nozzle device. A set of accurate rotational and 27Al and 14N nuclear quadrupole coupling constants have been determined from the analysis of the rotational spectrum and compared with those predicted in a high-level ab initio study, conducting to the assignment of the observed species to linear AlCCCN. We have searched for this species towards the carbon-rich evolved star IRC + 10216 but only an upper limit to its abundance has been obtained.
2017-03-09T09:28:25Z
2017-03-09T09:28:25Z
2014
info:eu-repo/semantics/article
The Journal of Chemical Physics 141, 104305 (2014)
0021-9606
http://uvadoc.uva.es/handle/10324/22510
10.1063/1.4894501
The Journal of Chemical Physics
eng
http://aip.scitation.org/doi/full/10.1063/1.4894501
info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
© 2014 AIP Publishing
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