2024-03-29T00:57:52Zhttp://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/170262024-01-30T09:54:58Zcom_10324_1186com_10324_931com_10324_894com_10324_28542com_10324_952col_10324_1404col_10324_28543
García Melchor, Max
Casares González, Juan Ángel
Espinet Rubio, Pablo
2016-05-30T11:26:19Z
2016-05-30T11:26:19Z
2016
Chem. Commun., 2016, 52, 4305-4308
1364-548X
http://uvadoc.uva.es/handle/10324/17026
10.1039/C5CC10496C
4305
4308
Chemical Communications
52
Producción Científica
The mechanism of Ph/X exchange in reactions involving SnPhnBu3 and [AuXL] complexes switches dramatically from the usual concerted mechanism involving Ar/X mixed bridges when X = Cl, to an unexpected oxidative addition/reductive elimination pathway via an AuIII intermediate when X = vinyl.
application/pdf
eng
Royal Society of Chemistry
info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Attribution 4.0 International
Reacciones químicas
Dramatic Mechanistic Switch in Sn/AuI Group Exchanges: Transmetalation vs. Oxidative Addition
info:eu-repo/semantics/article
http://dx.doi.org/10.1039/C5CC10496C
SI