2024-03-29T00:50:12Zhttp://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/217092021-06-24T07:43:16Zcom_10324_1186com_10324_931com_10324_894com_10324_28542com_10324_952col_10324_1404col_10324_28543
The stille reaction, 38 years later
Cordovilla, Carlos
Bartolomé Albistegui, María del Camino
Martínez de Ilarduya Martínez de Ilarduya, Jesús María
Espinet Rubio, Pablo
Stille cross-coupling
Producción Científica
The first now named Stille reaction was published 38 years ago, and
the last comprehensive revision of this catalysis was in 2004. Since then the
knowledge of the different steps of the three possible (and sometimes competing)
reaction pathways (cyclic, open, and ionic) has been almost completed by synergistic
experimental and theoretical studies: the Stille reaction is perhaps the best characterized
catalytic process if we consider the number of intermediates that have
been detected. This review concentrates on the mechanistic new knowledge, and
on important aspects as the revolution with the use of bulky phosphines, the bimetallic
alternative of the Stille reaction, the enantioselectivity in Stille and palladium
free Stille processes, the meaning of copper effect, or the possible approaches to
make Stille coupling a greener process.
Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. GR 169 and VA256U13)
Ministerio de Economía, Industria y Competitividad (CTQ2013-48406-P)
2016-12-14T11:35:42Z
2016-12-14T11:35:42Z
2015
info:eu-repo/semantics/article
ACS Catalysis 2015, 5 (5), p. 3040–3053
2155-5435
http://uvadoc.uva.es/handle/10324/21709
10.1021/acscatal.5b00448
3040
5
3053
ACS Catalysis
eng
Attribution-NonCommercial-NoDerivatives 4.0 International
info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
application/pdf
American Chemical Society
https://uvadoc.uva.es/bitstream/10324/21709/6/STILLER-PostP_ACS%20Catal.%202015.pdf.jpg
Hispana
TEXT
http://creativecommons.org/licenses/by-nc-nd/4.0/
UVaDOC. Repositorio Documental de la Universidad de Valladolid
http://uvadoc.uva.es/handle/10324/21709