2024-03-30T03:46:29Zhttp://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/370142021-06-24T07:43:25Zcom_10324_28542com_10324_952com_10324_894col_10324_28543
Pérez Iglesias, María
Lozano Lavilla, Olmo
Casares González, Juan Ángel
2019-07-16T07:51:32Z
2019-07-16T07:51:32Z
2019
Organometallics, 2019, vol. 38, n. 4. p. 739-742
0276-7333
http://uvadoc.uva.es/handle/10324/37014
https://doi.org/10.1021/acs.organomet.8b00885
The copper compound [Cu(C6Cl2F3)(tht)]4 (1) (tht: tetrahydrothiophene)
is an excellent catalyst for the trans- to cis- isomerization of
complexes [PdAr2(tht)2](Ar: fluoroaryl) and also for the exchange of aryls
between those palladium complexes. Herein, we also communicate the synthesis
and characterization of 1, and some of its derivatives. The x-ray structure
of 1 shows a linear chain of copper atoms, supported by fluoroaryl rings.
The NMR 19F-DOSY study indicates that this structure is preserved in solution
although in equilibrium with other species.
eng
info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
© 2019 American Chemical Society
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
[Cu(C6Cl2F3)(tht)]4: An Extremely Efficient Catalyst for the Aryl Scrambling between Palladium Complexes
info:eu-repo/semantics/article