2024-03-29T15:58:11Zhttp://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/234722021-07-06T08:34:13Zcom_10324_1186com_10324_931com_10324_894col_10324_1404
Furanosic forms of sugars: conformational equilibrium of methyl beta-D-ribofuranoside
Écija, Patricia
Uriarte, Iciar
Spada, Lorenzo
Davis, Benjamin
Caminati, Walther
Basterretxea, Francisco José
Lesarri Gómez, Alberto Eugenio
Cocinero, Alberto
Química
The investigation of an isolated ribofuranose unit in the gas phase
reveals the intrinsic conformational landscape of the biologically
active sugar form.We report the rotational spectra of two conformers
of methyl b-D-ribofuranoside in a supersonic jet expansion. Both
conformers adopt a near twisted (3T2) ring conformation with the
methoxy and hydroxymethyl substituents involved in various intramolecular
hydrogen bonds.
2017-06-09T19:04:55Z
2017-06-09T19:04:55Z
2017-06-09T19:04:55Z
2016
info:eu-repo/semantics/article
ChemComm, 2016, 52, 6241
1359-7345
http://uvadoc.uva.es/handle/10324/23472
10.1039/c6cc01180b
6241
6244
Chemical Communications
52
spa
info:eu-repo/semantics/openAccess
Royal Society of Chemistry