RT info:eu-repo/semantics/article
T1 Accurate experimental (p, ρ, T) data for the introduction of hydrogen into the natural gas grid: Thermodynamic characterization of the nitrogen-hydrogen binary system from 240 K to 350 K and pressures up to 20 MPa
A1 Hernández Gómez, Roberto
A1 Tuma, Dirk
A1 Gómez Hernández, Ángel
A1 Chamorro Camazón, César Rubén
K1 Termodinámica
K1 Density
K1 Equation of state
K1 Hydrogen
K1 Natural gas
K1 Nitrogen
K1 Single-sinker densimeter
AB The experimental density data of the binary system nitrogen-hydrogen available at the time of the development of the equation of state for natural gases and related mixtures, GERG-2008, were limited to hydrogen contents higher than 0.15 (amount-of-substance fraction) and temperatures above 270 K. This work provides accurate experimental (p, ρ, T) data for three binary mixtures of nitrogen and hydrogen: (0.95 N2 + 0.05 H2), (0.90 N2 + 0.10 H2), and (0.50 N2 + 0.50 H2) at temperatures of (240, 250, 260, 275, 300, 325, and 350) K, thus extending the range of available experimental data to low hydrogen contents and low temperatures. The density measurements were performed by using a single-sinker densimeter with magnetic suspension coupling at pressures up to 20 MPa. Experimental data were compared with the corresponding densities calculated from the GERG-2008 and the AGA8-DC92 equations of state. The relative deviations of the experimental data from both equations of state were within the estimated uncertainty value of the equations. Therefore, the experimental data agree very well with the values estimated from the equations. The virial coefficients B(T,x), C(T,x), and D(T,x) as well as the second interaction virial coefficient   for the nitrogen-hydrogen binary system were also calculated from the experimental data set at temperatures from (240 to 350) K. The resulting values agree with those from literature.
PB American Chemical Society Publications
SN 0021-9568
YR 2017
FD 2017
LK http://uvadoc.uva.es/handle/10324/29088
UL http://uvadoc.uva.es/handle/10324/29088
LA eng
NO J. Chem. Eng. Data 2017, 62, 4310-4326
DS UVaDOC
RD 18-abr-2024