RT info:eu-repo/semantics/article
T1 α-Substituted Benzylic Complexes of Palladium(II) as Precursors of Palladium Hydrides
A1 Martín Ruiz, Blanca
A1 Pérez Ortega, Ignacio
A1 Albéniz Jiménez, Ana Carmen
K1 Chemistry
K1 Organometallic Chemistry
K1 Palladium
K1 Benzyl complexes
K1 Hydrides
K1 Transmetalation
AB The adoption of a pseudoallylic (η3) form makes palladium benzylic derivatives a class of stabilized palladium alkyls that can undergo β-H elimination reactions in a more controlled way. α-(Pentafluorophenylmethyl)benzyl palladium complexes have been studied and theydecompose by β-H elimination to give palladium hydrides that, depending on the auxil-iary ligands can: a) transmetalate to another palladium atom and, by reductive elimina- tion, give hydrogenated products; this process is favored for a combination of bridging ligands (i.e halogens) and low coordinating ligands. b) Be used as a hydride source and get trapped by a diene to give palladium allylic derivatives. The presence of carbon mon- oxide does not induce a β-H elimination reactions and only CO insertion into the Pd- benzyl bond to give acyl derivatives is observed.
PB American Chemical Society
YR 2018
FD 2018
LK http://uvadoc.uva.es/handle/10324/31461
UL http://uvadoc.uva.es/handle/10324/31461
LA eng
NO Organometallics, 2018, vol. 37, p. 1665-1670
DS UVaDOC
RD 26-abr-2024