RT info:eu-repo/semantics/article
T1 Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
A1 Plajer, Alex J.
A1 Kopf, Sara
A1 Colebatch, Annie Louise
A1 Bond, Andrew D.
A1 Wright, Dominic Simon
A1 García Rodríguez, Raúl
K1 Supramolecular chemistry
K1 Química supramolecular
K1 Aluminate
K1 Aluminato
AB Post-functionalisation of the aluminate anion [EtAl(6-R-2-py)3]− (6-R-2-py = 6-R-2-pyridyl, R = Me or Br) can be accomplished via nucleophilic addition of the pyridyl groups to the electrophilic C[double bond, length as m-dash]O group of aldehydes (RCH[double bond, length as m-dash]O) or by deprotonation of carboxylic acids (RCO2H). NMR spectroscopic and crystallographic studies show how 6-Me-2-py groups can detect chirality and reveal a new aspect of isomerism.
PB Royal Society of Chemistry
SN 1477-9234
YR 2019
FD 2019
LK http://uvadoc.uva.es/handle/10324/39918
UL http://uvadoc.uva.es/handle/10324/39918
LA eng
NO Dalton Transactions, 2019, vol. 48, n. 17. p. 5692-5697
NO Producción Científica
DS UVaDOC
RD 27-abr-2024