TY - JOUR AU - Villar, Pedro AU - Pérez Temprano, Mónica H. AU - Casares González, Juan Ángel AU - Álvarez, Rosana AU - Espinet Rubio, Pablo AU - Villar, Pedro PY - 2020 SN - 0276-7333 UR - http://uvadoc.uva.es/handle/10324/42910 AB - The aryl transmetalation processes between cis-[PdRf2(AsPh3)2] (Rf = C6Cl2F3) and [AuPf(AsPh3)] (Pf = C6F5) has been studied experimentally and by DFT calculations. Aryl exchange with or without isomerization of the Pd geometry occurs by ligand... LA - spa PB - American Chemical Society TI - Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5 or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution DO - 10.1021/acs.organomet.0c00245 ER -