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Dramatic Mechanistic Switch in Sn/AuI Group Exchanges: Transmetalation vs. Oxidative Addition
dc.contributor.authorGarcía Melchor, Max
dc.contributor.authorCasares González, Juan Ángel 
dc.contributor.authorEspinet Rubio, Pablo 
dc.date.accessioned2016-05-30T11:26:19Z
dc.date.available2016-05-30T11:26:19Z
dc.date.issued2016
dc.identifier.citationChem. Commun., 2016, 52, 4305-4308es
dc.identifier.issn1364-548Xes
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/17026
dc.descriptionProducción Científicaes
dc.description.abstractThe mechanism of Ph/X exchange in reactions involving SnPhnBu3 and [AuXL] complexes switches dramatically from the usual concerted mechanism involving Ar/X mixed bridges when X = Cl, to an unexpected oxidative addition/reductive elimination pathway via an AuIII intermediate when X = vinyl.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectReacciones químicases
dc.titleDramatic Mechanistic Switch in Sn/AuI Group Exchanges: Transmetalation vs. Oxidative Additiones
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1039/C5CC10496Ces
dc.relation.publisherversionhttp://dx.doi.org/10.1039/C5CC10496C
dc.identifier.publicationfirstpage4305es
dc.identifier.publicationlastpage4308es
dc.identifier.publicationtitleChemical Communicationses
dc.identifier.publicationvolume52es
dc.peerreviewedSIes
dc.rightsAttribution 4.0 International


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