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dc.contributor.author | Álvarez González, Celedonio Manuel | |
dc.contributor.author | García Rodríguez, Raúl | |
dc.contributor.author | Miguel San José, Daniel | |
dc.date.accessioned | 2018-03-19T12:23:42Z | |
dc.date.available | 2018-03-19T12:23:42Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Dalton Transactions 2016, 45 , pp. 963 – 972 | es |
dc.identifier.issn | 1477-9226 | es |
dc.identifier.uri | http://uvadoc.uva.es/handle/10324/29152 | |
dc.description | Producción Científica | es |
dc.description.abstract | Metallamacrocycles of 12, 16, and 22 members are obtained by deprotonation of the carboxylic group of the side chain of iminopyridine complexes derived from the amino acid β-alanine, and the peptides Gly–Gly and Gly–Gly–Gly. Instead of the expected intramolecular attack to give tridentate (N,N,O) ligands, the deprotonated carboxylate attacks in an inter-molecular manner to give dimers in which the ligand acts as a bridge bonded in a κ2(N,N′) chelating fashion to one metal and as κ(O) to the other metal. The formation of the dimers is supported by NMR spectroscopy, mass spectrometry and X-ray crystallography. | es |
dc.format.mimetype | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject.classification | Metallamacrocycle | es |
dc.title | Metallamacrocycle formation through dimerization of metal bioconjugates derived from amino acids and peptides | es |
dc.type | info:eu-repo/semantics/article | es |
dc.identifier.doi | 10.1039/C5DT01256B | es |
dc.relation.publisherversion | http://pubs.rsc.org/en/content/articlelanding/2016/dt/c5dt01256b#!divAbstract | es |
dc.peerreviewed | SI | es |
dc.description.project | Ministerio de Economía, Industria y Competitividad (Project CTQ2013-41067-P) | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International |
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