Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling

Ponce de León Pintado, Jaime; Espinet Rubio, Pablo

doi:10.1039/d1cc04915a

Título

Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling

dc.contributor.author	Ponce de León Pintado, Jaime
dc.contributor.author	Espinet Rubio, Pablo
dc.date.accessioned	2023-04-28T12:09:22Z
dc.date.available	2023-04-28T12:09:22Z
dc.date.issued	2021
dc.identifier.citation	Chemical Communications, 2021, 57, 10875–10878	es
dc.identifier.issn	1359-7345	es
dc.identifier.uri	https://uvadoc.uva.es/handle/10324/59422
dc.description	Producción Científica	es
dc.description.abstract	Highly selective cross-couplings to polyfluorinated assymmetric biaryls, including the symmetric biaryl C6F5–C6F5, are achieved at relatively low temperature (80 °C) and in short times using [MCl2(PhPEWO-F)] catalysts (M = Ni, Pd; PhPEWO-F = 1-(PPh2), 2-(CH[double bond, length as m-dash]CH–C(O)Ph)–C6F4), ArFI, and Zn(C6F5)2 as example of highly fluorinated nucleophile.	es
dc.format.mimetype	application/pdf	es
dc.language.iso	eng	es
dc.publisher	Royal Society of Chemistry	es
dc.rights.accessRights	info:eu-repo/semantics/openAccess	es
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject.classification	Negishi cross-coupling	es
dc.subject.classification	Acoplamiento de Negishi	es
dc.subject.classification	Cross-coupling reaction catalyzed	es
dc.subject.classification	Reacción de acoplamiento cruzado	es
dc.title	Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling	es
dc.type	info:eu-repo/semantics/article	es
dc.rights.holder	© 2021 Royal Society of Chemistry	es
dc.identifier.doi	10.1039/d1cc04915a	es
dc.relation.publisherversion	https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc04915a	es
dc.identifier.publicationfirstpage	10875	es
dc.identifier.publicationissue	83	es
dc.identifier.publicationlastpage	10878	es
dc.identifier.publicationtitle	Chemical Communications	es
dc.identifier.publicationvolume	57	es
dc.peerreviewed	SI	es
dc.identifier.essn	1364-548X	es
dc.rights	Attribution-NonCommercial-NoDerivatives 4.0 Internacional	*
dc.type.hasVersion	info:eu-repo/semantics/acceptedVersion	es
dc.subject.unesco	23 Química	es

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