RT info:eu-repo/semantics/article T1 Production of volatile fatty acids (VFAs) from five commercial bioplastics via acidogenic fermentation A1 García Depraect, Octavio A1 Lebrero Fernández, Raquel A1 Rodriguez Vega, Sara A1 Börner, Rosa Aragão A1 Börner, Tim A1 Muñoz Torre, Raúl K1 Biodegradation K1 Biodegradación K1 Biorefinery K1 Biorrefinería K1 Polyhydroxyalkanoates K1 Polihidroxialcanoatos AB The feasibility of producing volatile fatty acids (VFAs) from five commercial bioplastics via acidogenic fermentation by a non-pretreated anaerobic sludge was investigated. Mesophilic, anaerobic, acidogenic batch assays at 1, 10 and 20 g/L feed concentrations revealed the feasibility of producing VFAs from polyhydroxyalkanoates (PHA), i.e., PHB and PHBV, but not from PBS, PCL and PLA under the test conditions and time. However, only high PHA substrate concentrations (10–20 g/L) resulted in organic overloading and decreasing the pH of the culture broth down to 4–5, which in turn induced the accumulation of VFAs via kinetic imbalance between acidogenesis and methanogenesis. Gaseous carbon (C-CO2 and C-CH4) accounted for 8–35% of the total initial carbon, while C-VFAs represented 10–18%, mainly as acetate and butyrate. This study represents the first systematically assessed proof-of-concept to produce VFAs from PHA, which is key for the design of bioplastic-to-bioplastic recycling (bio)technologies. PB Elsevier SN 0960-8524 YR 2022 FD 2022 LK https://uvadoc.uva.es/handle/10324/54163 UL https://uvadoc.uva.es/handle/10324/54163 LA eng NO Bioresource Technology, 2022, In Press, 127655 NO Producción Científica DS UVaDOC RD 15-jun-2024