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<title>DEP63 - Comunicaciones a congresos, conferencias, etc.</title>
<link>https://uvadoc.uva.es/handle/10324/1406</link>
<description>Dpto. Química Física y Química Inorgánica - Comunicaciones a congresos, conferencias, etc.</description>
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<dc:date>2026-04-07T03:06:18Z</dc:date>
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<title>Corannulene-Based Reversible Bistable Molecular Machines for Fullerene Recognition</title>
<link>https://uvadoc.uva.es/handle/10324/58237</link>
<description>A molecular machine refers to a multistable chemical system capable of reversibly modify its structure by a relative movement of its constituent parts as a response to an external stimulus producing observable work. They are actually key functional elements that support life itself in all living beings.&#13;
In this talk we will focus on artificial molecular machines which switch their structure between two well-defined conformers/configurational isomers by photoisomerization, metal coordination/decoordination, and redox process. All the species presented bear two units of corannulene (C20H10), a geodesic polyarene capable of establishing attractive interactions with fullerenes through concave-convex π-π interactions. The operational principle relies on the formation or disruption of a molecular tweezer by placing two corannulene units in the right location to establish a cavity for fullerene recognition. Their switching properties, especially the in-situ reversibility, and the impact produced onto their ability to recognize fullerenes (C60, C70) will be shown and discussed.
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<dc:date>2022-01-01T00:00:00Z</dc:date>
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