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dc.contributor.authorGuevara Pulido, James Oswaldo
dc.contributor.authorAndrés García, José María 
dc.contributor.authorÁvila, Deisy P.
dc.contributor.authorPedrosa Sáez, Rafael 
dc.date.accessioned2016-12-05T13:48:27Z
dc.date.available2016-12-05T13:48:27Z
dc.date.issued2016
dc.identifier.citationRSC Advances, 2016, 6, p. 30166-30169es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/21452
dc.descriptionProducción Científicaes
dc.description.abstractUnprecedented diastereo- and enantioselective synthesis of seven-membered rings has been achieved by organocatalyzed intramolecular Michael addition of enals bearing β-diketone functionality. The cyclization leads to 2,3-disubstituted cycloheptanone derivatives in high yield and excellent stereoselectivity. The same organocatalyzed cyclization process has been used to prepare six-membered homologs, but with lower stereoselectivity.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectQuímica orgánicaes
dc.titleEnantioselective Synthesis of Seven-Membered Carbo- and Heterocyles by Organocatalyzed Intramolecular Michael Additiones
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1039/C6RA04198Aes
dc.relation.publisherversionhttp://pubs.rsc.org/es
dc.identifier.publicationfirstpage30166es
dc.identifier.publicationissue6es
dc.identifier.publicationlastpage30169es
dc.identifier.publicationtitleRSC Advanceses
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (CTQ 2011-28487)es
dc.description.projectJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA064U13)es
dc.description.projectUniversidad de Valladolid for a pre-doctoral fellowshipses
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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