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Título
Formal Gold to Gold Transmetalation of an Alkynyl Group Mediated by Palladium: A Bisalkynyl Gold Complex as a Ligand to Palladium
dc.contributor.authorToledo Pérez, Alberto 
dc.contributor.authorMeana, Isabel
dc.contributor.authorAlbéniz Jiménez, Ana Carmen 
dc.date.accessioned2016-12-14T11:49:20Z
dc.date.available2016-12-14T11:49:20Z
dc.date.issued2015
dc.identifier.citationChemistry - A European Journal, 2015, Volume 21, Issue 38, p. 13216–13220es
dc.identifier.issn2155-5435es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/21711
dc.descriptionProducción Científicaes
dc.description.abstractThe reaction of [Au(C≡CnBu)]n with [Pd(η3-allyl)Cl(PPh3)] results in a ligand and alkynyl rearrangement, and leads to the heterometallic complex [Pd(η3-allyl){Au(C≡CnBu)2}]2 (3) with an unprecedented bridging bisalkynyl gold ligand coordinated to palladium. This is a formal gold to gold transmetalation that occurs through reversible alkynyl transmetalations between gold and palladium.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectPalladiumes
dc.titleFormal Gold to Gold Transmetalation of an Alkynyl Group Mediated by Palladium: A Bisalkynyl Gold Complex as a Ligand to Palladiumes
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1021/acscatal.6b01825es
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (CTQ2013-48406-P)es
dc.description.projectJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA064U13)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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