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dc.contributor.authorPeña Calvo, María Isabel 
dc.contributor.authorKolesnikova, Lucie
dc.contributor.authorCabezas, Carlos
dc.contributor.authorBermúdez Arias, María Celina
dc.contributor.authorBerdakin, Matías
dc.contributor.authorSimão, Alcides
dc.contributor.authorAlonso Hernández, José Luis 
dc.date.accessioned2017-03-19T17:20:47Z
dc.date.available2017-03-19T17:20:47Z
dc.date.issued2014
dc.identifier.citationPhysical Chemistry Chemical Physics, 2014,16, 23244-23250es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/22655
dc.description.abstractThe bioactive amino monosaccharide D-glucosamine has been generated in gas phase via laser ablation of D-glucosamine hydrochloride. Three cyclic α- 4C1 pyranose forms have been identified using Fourier transform microwave techniques. Stereoelectronic hyperconjugative forces – essentially linked with the anomeric or gauche effect – and cooperative OH…O, OH…N and NH…O chains, extended along the entire molecule, are found to be the main factors driving the conformational behavior. The orientation of the NH2 group within each conformer has been determined by the values of the nuclear quadrupole constants. The results have been compared with those recently obtained for the archetypical D-glucose.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccesses
dc.titleThe shape of D-glucosaminees
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holderThe Royal Society of Chemistry 2014es
dc.identifier.doi10.1039/C4CP03593Ces
dc.peerreviewedSIes


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