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Título
The Rotational Spectrum of Tyrosine
Autor
Año del Documento
2015
Editorial
American Chemical Society
Descripción
Producción Científica
Documento Fuente
Journal of Physical Chemistry A, 2015, 119 (16), pp 3731–3735
Abstract
In this work neutral tyrosine has been generated in the gas phase by laser ablation of solid samples, and its most abundant conformers characterized through their rotational spectra. Their identification has been made by comparison between the experimental and ab initio values of the rotational and quadrupole coupling constants. Both conformers are stabilized by an O–H•••N hydrogen bond established within the amino acid skeleton chain and an additional weak N–H•••π hydrogen bond. The observed conformers differ in the orientation of the phenolic −OH group.
Palabras Clave
Tirosina
Revisión por pares
SI
Patrocinador
Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA175U13)
Version del Editor
Propietario de los Derechos
© American Chemical Society
Idioma
eng
Derechos
openAccess
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