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dc.contributor.authorMolina de la Torre, Jesús A.
dc.contributor.authorAlbéniz Jiménez, Ana Carmen 
dc.date.accessioned2018-02-20T17:17:27Z
dc.date.available2018-02-20T17:17:27Z
dc.date.issued2017
dc.identifier.citationEur. J. Inorg. Chem. 2017, 2911–2919es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/28625
dc.descriptionProducción Científicaes
dc.description.abstractα-Diimine polymeric ligands have been synthesized using the bicyclic norbornane structure, present in vinylic-addi- tion polynorbornene ( VA-PNB). The VA-PNB–diimine ligands have been prepared by functionalization of the copolymer ob- tained by Ni-catalyzed polymerization of norbornene and nor- bornenylcarbonate. Immobilized palladium complexes of the type VA-PNB–diimine–PdX2 have been prepared, and their cata- lytic activity has been tested. The trifluoroacetato complex (X =CF3COO) can be used as a recyclable precatalyst in the Suzuki reaction. It is the source of minute amounts of homogeneous palladium active species, which carry out the catalysis with high turnover numbers. The recovered polymeric complex can be reused several times with no significant loss of activity. The polymeric analogue to Brookhart's catalyst, VA-PNB–diimine– PdMeCl, can also polymerize ethylene, although it is less active than its monomeric counterparts.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subjectChemistryes
dc.subject.classificationSupported catalystses
dc.subject.classificationPalladiumes
dc.subject.classificationPolynorborneneses
dc.subject.classificationdiimineses
dc.subject.classificationcross-couplinges
dc.titleα-Diimine–Palladium Complexes Incorporated in Vinylic- Addition Polynorbornenes: Synthesis and Catalytic Activityes
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1002/ejic.201700323es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/ejic.201700323
dc.identifier.publicationfirstpage2911es
dc.identifier.publicationlastpage2919es
dc.identifier.publicationtitleEuropean Journal of Inorganic Chemistryes
dc.peerreviewedSIes
dc.description.projectMINECO-SGPI, grant CTQ2013-48406-Pes
dc.description.projectMINECO-SGPI, grant CTQ2016-80913-Pes
dc.description.projectJunta de Castilla y León, grant VA302U13es


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