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| dc.contributor.author | Peñas de Frutos, Marconi Nicolás | |
| dc.contributor.author | Bartolomé Albistegui, María del Camino | |
| dc.contributor.author | García Melchor, Max | |
| dc.contributor.author | Espinet Rubio, Pablo | |
| dc.date.accessioned | 2018-02-28T20:07:29Z | |
| dc.date.available | 2019-04-04T23:40:14Z | |
| dc.date.issued | 2018 | |
| dc.identifier.citation | Chemical Communications, 2018, 54, 8, p. 984-987 | es |
| dc.identifier.issn | 1359-7345 | es |
| dc.identifier.uri | http://uvadoc.uva.es/handle/10324/28845 | |
| dc.description | Producción Científica | es |
| dc.description.abstract | Experiments mixing the stable 16e 5-coordinate complexes [RhCp*Ar2] (Cp* = C5Me5; Ar = C6F5, C6F3Cl2-3,5) uncover fast aryl transmetalations. Unexpectedly, as supported computationally, these exchanges are not spontaneous, but catalyzed by minute amounts of 18e (μ-OH)2[RhCp*Ar]2 as a source of 16e [RhCp*Ar(OH)]. The OH group is an amazingly efficient bridging partner to diminish the activation barrier of transmetalation. | es |
| dc.format.mimetype | application/pdf | es |
| dc.language.iso | eng | es |
| dc.publisher | Royal Society of Chemistry | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject.classification | Transmetalación | es |
| dc.title | Hidden aryl-exchange processes in stable 16e RhIII [RhCp*Ar2] complexes, and their unexpected transmetalation mechanism | es |
| dc.type | info:eu-repo/semantics/article | es |
| dc.identifier.doi | http://dx.doi.org/10.1039/C7CC09352G | es |
| dc.relation.publisherversion | http://pubs.rsc.org/en/content/articlelanding/2018/cc/c7cc09352g | es |
| dc.identifier.publicationtitle | Chemical Communications | es |
| dc.peerreviewed | SI | es |
| dc.description.embargo | 2019-04-04 | es |
| dc.description.project | Ministerio de Economía, Industria y Competitividad (Projects CTQ2016-80913-P and CTQ2014-52796-P) | es |
| dc.description.project | Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA051P17) | es |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International |
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