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dc.contributor.authorPeñas de Frutos, Marconi Nicolás 
dc.contributor.authorBartolomé Albistegui, María del Camino 
dc.contributor.authorGarcía Melchor, Max
dc.contributor.authorEspinet Rubio, Pablo 
dc.date.accessioned2018-02-28T20:07:29Z
dc.date.available2019-04-04T23:40:14Z
dc.date.issued2018
dc.identifier.citationChemical Communications, 2018, 54, 8, p. 984-987es
dc.identifier.issn1359-7345es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/28845
dc.descriptionProducción Científicaes
dc.description.abstractExperiments mixing the stable 16e 5-coordinate complexes [RhCp*Ar2] (Cp* = C5Me5; Ar = C6F5, C6F3Cl2-3,5) uncover fast aryl transmetalations. Unexpectedly, as supported computationally, these exchanges are not spontaneous, but catalyzed by minute amounts of 18e (μ-OH)2[RhCp*Ar]2 as a source of 16e [RhCp*Ar(OH)]. The OH group is an amazingly efficient bridging partner to diminish the activation barrier of transmetalation.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationTransmetalaciónes
dc.titleHidden aryl-exchange processes in stable 16e RhIII [RhCp*Ar2] complexes, and their unexpected transmetalation mechanismes
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doihttp://dx.doi.org/10.1039/C7CC09352Ges
dc.relation.publisherversionhttp://pubs.rsc.org/en/content/articlelanding/2018/cc/c7cc09352ges
dc.identifier.publicationtitleChemical Communicationses
dc.peerreviewedSIes
dc.description.embargo2019-04-04es
dc.description.projectMinisterio de Economía, Industria y Competitividad (Projects CTQ2016-80913-P and CTQ2014-52796-P)es
dc.description.projectJunta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA051P17)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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