• español
  • English
  • français
  • Deutsch
  • português (Brasil)
  • italiano
    • español
    • English
    • français
    • Deutsch
    • português (Brasil)
    • italiano
    • español
    • English
    • français
    • Deutsch
    • português (Brasil)
    • italiano
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of UVaDOCCommunitiesBy Issue DateAuthorsSubjectsTitles

    My Account

    Login

    Statistics

    View Usage Statistics

    Share

    View Item 
    •   UVaDOC Home
    • SCIENTIFIC PRODUCTION
    • Institutos de Investigación
    • Instituto Universitario Centro de Innovación en Química y Materiales Avanzados (CINQUIMA)
    • CINQUIMA - Artículos de revista
    • View Item
    •   UVaDOC Home
    • SCIENTIFIC PRODUCTION
    • Institutos de Investigación
    • Instituto Universitario Centro de Innovación en Química y Materiales Avanzados (CINQUIMA)
    • CINQUIMA - Artículos de revista
    • View Item
    • español
    • English
    • français
    • Deutsch
    • português (Brasil)
    • italiano

    Export

    RISMendeleyRefworksZotero
    • edm
    • marc
    • xoai
    • qdc
    • ore
    • ese
    • dim
    • uketd_dc
    • oai_dc
    • etdms
    • rdf
    • mods
    • mets
    • didl
    • premis

    Citas

    Por favor, use este identificador para citar o enlazar este ítem:http://uvadoc.uva.es/handle/10324/31461

    Título
    α-Substituted Benzylic Complexes of Palladium(II) as Precursors of Palladium Hydrides
    Autor
    Martín Ruiz, Blanca
    Pérez Ortega, IgnacioAutoridad UVA Orcid
    Albéniz Jiménez, Ana CarmenAutoridad UVA Orcid
    Año del Documento
    2018
    Editorial
    American Chemical Society
    Documento Fuente
    Organometallics, 2018, vol. 37, p. 1665-1670
    Abstract
    The adoption of a pseudoallylic (η3) form makes palladium benzylic derivatives a class of stabilized palladium alkyls that can undergo β-H elimination reactions in a more controlled way. α- (Pentafluorophenylmethyl)benzyl palladium complexes have been studied and they decompose by β-H elimination to give palladium hydrides that, depending on the auxil- iary ligands can: a) transmetalate to another palladium atom and, by reductive elimina- tion, give hydrogenated products; this process is favored for a combination of bridging ligands (i.e halogens) and low coordinating ligands. b) Be used as a hydride source and get trapped by a diene to give palladium allylic derivatives. The presence of carbon mon- oxide does not induce a β-H elimination reactions and only CO insertion into the Pd- benzyl bond to give acyl derivatives is observed.
    Materias (normalizadas)
    Chemistry
    Organometallic Chemistry
    Palabras Clave
    Palladium
    Benzyl complexes
    Hydrides
    Transmetalation
    Revisión por pares
    SI
    DOI
    10.1021/acs.organomet.8b00066
    Patrocinador
    MINECO (SGPI, grant CTQ2016-80913-P)
    Version del Editor
    https://pubs.acs.org/doi/10.1021/acs.organomet.8b00066
    Idioma
    eng
    URI
    http://uvadoc.uva.es/handle/10324/31461
    Derechos
    openAccess
    Collections
    • CINQUIMA - Artículos de revista [162]
    • DEP63 - Artículos de revista [322]
    Show full item record
    Files in this item
    Nombre:
    Organometallics-2018-37-1665−1670submitted-manuscript.pdf
    Tamaño:
    519.1Kb
    Formato:
    Adobe PDF
    Thumbnail
    FilesOpen

    Universidad de Valladolid

    Powered by MIT's. DSpace software, Version 5.10