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| dc.contributor.author | Neves García, Tomaz | |
| dc.contributor.author | Vélez Blasco, Andrea | |
| dc.contributor.author | Martínez de Ilarduya Martínez de Ilarduya, Jesús María | |
| dc.contributor.author | Espinet Rubio, Pablo | |
| dc.date.accessioned | 2018-11-14T08:09:16Z | |
| dc.date.available | 2018-11-14T08:09:16Z | |
| dc.date.issued | 2018 | |
| dc.identifier.citation | Chemical Communications, 2018,54, 11809-11812 | es |
| dc.identifier.issn | 1359-7345 | es |
| dc.identifier.uri | http://uvadoc.uva.es/handle/10324/32631 | |
| dc.description | Producción Científica | es |
| dc.description.abstract | Chiral-diamine catalyzed addition of ZnMe2 to PhC(O)CF2X (in dichloromethane at −30 °C) affords fluorinated alkyl tertiary alcohols in high yield (quantitative for X = H, F, Cl; 84% for X = CF3) and up to 99% ee. These conditions are similarly very efficient for other various ArC(O)CF3 molecules. A fine analysis of the results can be performed based on a double-cycle mechanism. | es |
| dc.format.mimetype | application/pdf | es |
| dc.language.iso | eng | es |
| dc.publisher | Royal Society of Chemistry | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject.classification | Química organometálica | es |
| dc.subject.classification | Organometallic chemistry | es |
| dc.title | Highly enantioselective addition of dimethylzinc to fluorinated alkyl ketones, and the mechanism behind it | es |
| dc.type | info:eu-repo/semantics/article | es |
| dc.rights.holder | © 2018 Royal Society of Chemistry | |
| dc.identifier.doi | https://doi.org/10.1039/C8CC06358C | es |
| dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc06358c#!divAbstract | es |
| dc.peerreviewed | SI | es |
| dc.description.project | Ministerio de Economía, Industria y Competitividad (Projects CTQ-2016-80913-P and CTQ2014-52796) | es |
| dc.description.project | Junta de Castilla y León (programa de apoyo a proyectos de investigación - Ref. VA051P17) | es |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | |
| dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion |
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