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    Por favor, use este identificador para citar o enlazar este ítem:http://uvadoc.uva.es/handle/10324/33401

    Título
    Flexible Bonding of the Phosph(V)azane Dianions [S(E)P(μ‐NtBu)]22−
    Autor
    Plajer, Alex J.
    García Rodríguez, RaúlAutoridad UVA Orcid
    Rizzuto, Felix J.
    Wright, Dominic Simon
    Año del Documento
    2018
    Editorial
    Wiley
    Descripción
    Producción Científica
    Documento Fuente
    Chemistry A European Journal, 2018, Volume 24, Issue 8,Pages 2013-2019
    Abstract
    Oxidation of the PIII dianion [S−P(μ‐NtBu)]22− (1) with elemental sulphur, selenium and tellurium gives the PV dianions [(S)(E)P(μ‐NtBu)]22− (E = S (6 a), Se (6 b), Te (6 c)). Although 6 c proves to be too unstable, the S,S‐dianion 6 a and ambidentate S,Se‐dianion 6 b are readily transferred intact to main group and transition metal elements, producing a range of new cage and coordination compounds. While their coordination characteristics are in many ways similar to closely‐related isoelectronic phosph(V)azane anions [(E)(RN=)P(μ‐NtBu)]22−, the sterically unhindered nature of 6 introduces an expanded range of coordination modes, that is, facial S,S‐ and Se,Se‐bonding as well as side‐on S,Se‐coordination. All of these bonding modes are observed for the amibidentate S,Se dianion 6 b.
    Palabras Clave
    Oxidación del dianión
    Oxidation of the dianion
    ISSN
    0947-6539
    Revisión por pares
    SI
    DOI
    10.1002/chem.201705413
    Patrocinador
    Ministerio de Economía, Industria y Competitividad - Agencia Estatal de Investigación (AEI)
    European Social Fund (ESF)
    Ramon y Cajal contract (RG-R, RYC-2015 -19035 )
    Version del Editor
    https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201705413
    Idioma
    eng
    URI
    http://uvadoc.uva.es/handle/10324/33401
    Derechos
    openAccess
    Collections
    • DEP63 - Artículos de revista [328]
    • MIOMeT - Artículos de revista [51]
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    Universidad de Valladolid

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