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dc.contributor.authorPlajer, Alex J.
dc.contributor.authorColebatch, Annie Louise
dc.contributor.authorRizzuto, Felix J.
dc.contributor.authorPröhm, Patrick
dc.contributor.authorBond, Andrew D.
dc.contributor.authorGarcía Rodríguez, Raúl 
dc.contributor.authorWright, Dominic Simon
dc.date.accessioned2018-12-11T11:17:39Z
dc.date.available2019-04-04T23:40:15Z
dc.date.issued2018
dc.identifier.citationAngewandte Chemie International Edition, 2018, Volume 57, Issue 22, 2018 Pages 6648-6652es
dc.identifier.issn1433-7851es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/33404
dc.descriptionProducción Científicaes
dc.description.abstractAlthough a multitude of studies have explored the coordination chemistry of classical tripodal ligands containing a range of main‐group bridgehead atoms or groups, it is not clear how periodic trends affect ligand character and reactivity within a single ligand family. A case in point is the extensive family of neutral tris‐2‐pyridyl ligands E(2‐py)3 (E=C−R, N, P), which are closely related to archetypal tris‐pyrazolyl borates. With the 6‐methyl substituted ligands E(6‐Me‐2‐py)3 (E=As, Sb, Bi) in hand, the effects of bridgehead modification alone on descending a single group in the periodic table were assessed. The primary influence on coordination behaviour is the increasing Lewis acidity (electropositivity) of the bridgehead atom as Group 15 is descended, which not only modulates the electron density on the pyridyl donor groups but also introduces the potential for anion selective coordination behaviour.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.titleHow Changing the Bridgehead Can Affect the Properties of Tripodal Ligandses
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doihttps://doi.org/10.1002/anie.201802350es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/anie.201802350es
dc.peerreviewedSIes
dc.description.embargo2019-04-04es
dc.description.projectMinisterio de Economía, Industria y Competitividad - Agencia Estatal de Investigación (AEI)es
dc.description.projectEuropean Social Fund (ESF)es
dc.description.projectRamón y Cajal contract (RG-R, RYC-2015–19035)es
dc.description.projectThe Leverhulme Trust (Grant for DSW and RG-R, postdoctoral fundng for ALC), The Cambridge Trust (Vice Chancellor Scholarship for AJP, Cambridge Australia Scholarship for FJR) , ZEDAT and FU Berlin (PP)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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