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dc.contributor.author | García Rodríguez, Raúl | |
dc.contributor.author | Kopf, Sara | |
dc.contributor.author | Wright, Dominic Simon | |
dc.date.accessioned | 2018-12-11T11:56:09Z | |
dc.date.available | 2019-01-17T00:40:19Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | Dalton Transactions, 2018, Issue 7, Pages 2232-2239 | es |
dc.identifier.issn | 1477-9226 | es |
dc.identifier.uri | http://uvadoc.uva.es/handle/10324/33406 | |
dc.description | Producción Científica | es |
dc.description.abstract | The coordination ability of tris(pyridyl)aluminates can be modified by the steric and electronic character of substituents at the 6-positions of their pyridyl rings. Whereas [EtAl(6-Me-2-py)3]− (1) coordinates strongly to lanthanide(II) ions [Eu(II) and Yb(II)], [EtAl(6-Br-2-py)3]− (2) forms much weaker complexes, and [EtAl(6-CF3-2-py)3]− does not coordinate at all. The modification of the donor ability of these ligands is investigated by solid-state studies of the Ln(II) sandwich compounds and by competitive coordination studies in solution. | es |
dc.format.mimetype | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject.classification | Química organometálica | es |
dc.subject.classification | Química bioinorgánica | es |
dc.subject.classification | Organometallic chemistry | es |
dc.subject.classification | Bioinorganic chemistry | es |
dc.title | Modifying the donor properties of tris(pyridyl)aluminates in lanthanide(II) sandwich compounds | es |
dc.type | info:eu-repo/semantics/article | es |
dc.identifier.doi | https://doi.org/10.1039/C7DT04657J | es |
dc.relation.publisherversion | https://pubs.rsc.org/en/Content/ArticleLanding/2018/DT/C7DT04657J | es |
dc.peerreviewed | SI | es |
dc.description.embargo | 2019-01-17 | es |
dc.description.project | Ministerio de Economía, Industria y Competitividad - Agencia Estatal de Investigación (AEI) | es |
dc.description.project | European Social Fund (ESF) | es |
dc.description.project | Ramón y Cajal contract (RG-R, RYC-2015–19035) | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International |
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