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dc.contributor.authorChico Robles, Rubén
dc.contributor.authorDomingo de la Rubia, Estela de 
dc.contributor.authorDomínguez, Cristina
dc.contributor.authorDonnio, Bertrand
dc.contributor.authorHeinrich, Benoît
dc.contributor.authorTermine, Roberto
dc.contributor.authorGolemme, Attilio
dc.contributor.authorCoco Cea, Silverio 
dc.contributor.authorEspinet Rubio, Pablo 
dc.date.accessioned2018-12-12T12:30:03Z
dc.date.available2018-12-12T12:30:03Z
dc.date.issued2017
dc.identifier.citationChemistry of Materials, 2017, 29 (17), pp 7587–7595es
dc.identifier.issn0897-4756es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/33433
dc.descriptionProducción Científicaes
dc.description.abstractThis paper reports the synthesis, liquid crystal behavior, and charge-transport properties in the mesophase of isocyano-triphenylene gold, copper, palladium, and platinum complexes [MX(CNR)] (CNR = 2-(6-(4-isocyanophenoxy)hexyloxy)-3,6,7,10,11-pentakisdodecyloxytriphenylene; M = Au, X = Cl, C6F5, C6F4OC10H21, CN; M = Cu, X = Cl), [(μ-4,4′-C6F4C6F4){Au(CNR)}2], [(μ-Cl2){Cu(CNR)2}2], and [MX2(CNR)2] (M = Pd, Pt; X = Cl, Br, I, and M = Pt, X = CN). The thermal and electronic properties of these materials are modulated by the metal fragment. The complexes that display columnar mesomorphism are those that support more than one triphenylene per molecule or those that produce a similar effect by dipole–dipole interactions between the metal groups. These circumstances improve the balance of favorable enthalpic interactions versus unfavorable entropic contributions into a columnar stacking. Hybrid inorganic/organic dual columnar mesophases with high SCLC hole mobility along the columnar stacking, above 1 cm2 V–1 s–1, have been found. It is worth noting that the dicyanoplatinum complex displays mesophase phosphorescence based on Pt···Pt interactions.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationCristal líquidoes
dc.subject.classificationLiquid crystales
dc.titleHigh One-Dimensional Charge Mobility in Semiconducting Columnar Mesophases of Isocyano-Triphenylene Metal Complexeses
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doihttps://doi.org/10.1021/acs.chemmater.7b02922es
dc.relation.publisherversionhttps://pubs.acs.org/doi/abs/10.1021/acs.chemmater.7b02922es
dc.peerreviewedSIes
dc.description.projectMinisterio de Ciencia e Innovación (Proyect CTQ2014-52796-P)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International


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