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dc.contributor.authorAlbéniz Jiménez, Ana Carmen 
dc.date.accessioned2019-09-09T11:12:16Z
dc.date.available2019-09-09T11:12:16Z
dc.date.issued2018
dc.identifier.citationEur. J. Inorg. Chem. 2018, 3693–3705es
dc.identifier.issn1434-1948es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/37804
dc.descriptionProducción Científicaes
dc.description.abstractPalladium complexes with carbene ligands are among the best known and more extensively used catalysts. Those carbenes are usually NHC or N,N-disubstituted derivatives and their use relies on the robust nature of the carbene ligands and their role as auxiliary ligands that modify the metal's elec- tronic and steric features. In contrast, there are other types of carbenes that, when coordinated to palladium, lead to transfor- mations in which the carbene fragment is involved. In the last decade, palladium-catalyzed reactions have been extended to the use of carbene precursors that can be functionalized with the formation of several C–C bonds in one reaction step. Plausi- ble mechanisms have been proposed where a carbene–hydro- carbyl coupling occurs in the palladium coordination sphere. This microreview aims to collect and discuss the examples of organometallic reactions in well-characterized palladium com- plexes where the carbene is one of the fragments involved in C–C bond formation. These examples are key in understanding and supporting the mechanisms proposed for the Pd-catalyzed of C–C coupling reactions of carbenes.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subjectQuímicaes
dc.titleReactive Palladium Carbenes: Migratory Insertion and Other Carbene-Hydrocarbyl Coupling Reactions on Well-Defined Systemses
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1002/ejic.201800597es
dc.identifier.publicationfirstpage3693es
dc.identifier.publicationissue33es
dc.identifier.publicationlastpage3705es
dc.identifier.publicationtitleEuropean Journal of Inorganic Chemistryes
dc.identifier.publicationvolume2018es
dc.peerreviewedSIes
dc.description.projectMINECO (SGPI, grant CTQ2016-80913-P)es
dc.description.projectJunta de Castilla y León (grants VA062G18 and VA051P17)es
dc.type.hasVersioninfo:eu-repo/semantics/draftes
dc.subject.unesco2303 Química Inorgánicaes
dc.subject.unesco2306 Química Orgánicaes


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