Show simple item record

dc.contributor.authorGarcía Loma, Rodrigo
dc.contributor.authorAlbéniz Jiménez, Ana Carmen 
dc.date.accessioned2019-09-09T11:35:15Z
dc.date.available2019-09-09T11:35:15Z
dc.date.issued2019
dc.identifier.citationAsian J. Org. Chem. 2019, 8, 304-315es
dc.identifier.issn2193-5807es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/37806
dc.description.abstractVinylic addition polynorbornenes (VA-PNB) result from the insertion polymerization of norbornene or specific norbornene derivatives catalyzed by transition metal com- plexes. The VA-PNB skeleton is completely aliphatic and keeps the bicyclic structure of norbornene. This saturated polymer is thermally and chemically very stable and it is a very robust scaffold to support catalysts or reagents for catalytic applications. Several VA-PNBs are now available with suitable functional groups (halogen, alkenyl, carbonates) that can be used as starting materials to introduce the functionalization of choice by post-polymerization reactions. This has been applied to anchor organocatalysts on VA-PNB as well as ligands that can be used to synthesize supported metal catalysts. The reported examples of the use of VA-PNB-linked catalysts and their recyclability will be presented. VA-PNBs have also proved useful in the context of organotin chemistry to solve the problem of tin contamination by an efficient separation and the reuse of tin byproducts. Its uses in the Stille cross-coupling reaction and tin-hydride radical proc- esses will be discussed.es
dc.format.mimetypeapplication/pdfes
dc.language.isospaes
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.subjectQuímicaes
dc.titleVinylic Addition Polynorbornene in Catalysises
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1002/ajoc.201800646es
dc.identifier.publicationfirstpage304es
dc.identifier.publicationissue3es
dc.identifier.publicationlastpage315es
dc.identifier.publicationtitleAsian Journal of Organic Chemistryes
dc.identifier.publicationvolume8es
dc.peerreviewedSIes
dc.description.projectMINECO (SGPI, grant CTQ2016-80913-P)es
dc.description.projectJunta de Castilla y León (grants VA062G18 and VA051P17 and a fellowship to RGL)es
dc.type.hasVersioninfo:eu-repo/semantics/submittedVersiones
dc.subject.unesco2303 Química Inorgánicaes
dc.subject.unesco2306 Química Orgánicaes
dc.subject.unesco2304 Química Macromoleculares


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record