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4-Pyridylisocyanide Gold(I) and Gold(I)-plus-Silver(I) Luminescent and Mechanochromic Materials: The Silver Role
dc.contributor.authorConejo Rodríguez, Verónica 
dc.contributor.authorPeñas de Frutos, Marconi Nicolás 
dc.contributor.authorEspinet Rubio, Pablo 
dc.date.accessioned2019-10-04T11:16:06Z
dc.date.available2019-10-04T11:16:06Z
dc.date.issued2019
dc.identifier.citationDalton Transactions, 2019, vol. 48, n. 28. p. 10412-10416es
dc.identifier.issn1477-9234es
dc.identifier.urihttp://uvadoc.uva.es/handle/10324/38372
dc.descriptionProducción Científicaes
dc.description.abstractCrystallographic and DFT examination of the metalloligands [AuAr(CNPy-4)] (Ar = C6F5 (1), C6F3Cl2-3,5 (2)) and their silver complexes [Ag[AuAr(CNPy-4)]2](BF4) (3 and 4) support that the marked luminescence red-shifts observed on moving from 1 to 2, from 1,2 to 3,4, or upon grinding, are not caused by electronic differences (either by changing the aryls C6F5/C6F3Cl2, or by N coordination to silver), nor by non-existent Au···Ag interactions. They are always due to structural changes disturbing stronger π-π stackings in order to allow for shorter Au···Au interactions.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectGoldes
dc.subjectOroes
dc.subject.classificationSilveres
dc.subject.classificationPlataes
dc.subject.classificationLuminescent materialses
dc.subject.classificationMateriales luminiscenteses
dc.subject.classificationMechanochromic materialses
dc.subject.classificationMateriales mecanocrómicoses
dc.title4-Pyridylisocyanide Gold(I) and Gold(I)-plus-Silver(I) Luminescent and Mechanochromic Materials: The Silver Rolees
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2019 Royal Society of Chemistryes
dc.identifier.doi10.1039/C9DT01618Jes
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2019/DT/C9DT01618J#!divAbstractes
dc.peerreviewedSIes
dc.description.projectMinisterio de Economía, Industria y Competitividad (grant CTQ2017-89217-P )es
dc.description.projectJunta de Castilla y León (project VA038G18)es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones
dc.subject.unesco2211.04 Cristalografíaes


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