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dc.contributor.authorAlonso Alonso, Elena Rita 
dc.contributor.authorLeón Ona, Iker 
dc.contributor.authorKolesnikova, Lucie
dc.contributor.authorMata, Santiago
dc.contributor.authorAlonso Hernández, José Luis 
dc.date.accessioned2021-08-19T10:25:43Z
dc.date.available2021-08-19T10:25:43Z
dc.date.issued2021
dc.identifier.citationAngewandte Chemie International Edition, 2021, vol. 60, n. 32, p. 17410-17414es
dc.identifier.issn1433-7851es
dc.identifier.urihttps://uvadoc.uva.es/handle/10324/47915
dc.descriptionProducción Científicaes
dc.description.abstractThe unbiased, naked structures of tartaric acid, one of the most important organic compounds existing in nature and a candidate to be present in the interstellar medium, has been revealed in this work for the first time. Solid samples of its naturally occurring (R,R) enantiomer have been vaporized by laser ablation, expanded in a supersonic jet, and characterized by Fourier transform microwave spectroscopy. In the isolation conditions of the jet, we have discovered up to five different structures stabilized by intramolecular hydrogen-bond networks dominated by O−H⋅⋅⋅O=C and O−H⋅⋅⋅O motifs extended along the entire molecule. These five forms, two with an extended (trans) disposition of the carbon chain and three with a bent (gauche) disposition, can serve as a basis to represent the shape of tartaric acid. This work also reports the first set of spectroscopy data that can be used to detect tartaric acid in the interstellar medium.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subject.classificationÁcido tartáricoes
dc.subject.classificationTartaric acides
dc.subject.classificationEspectroscopia rotacionales
dc.subject.classificationRotational spectroscopyes
dc.titleUnveiling five naked structures of tartaric acides
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2021 The Authorses
dc.identifier.doi10.1002/anie.202105718es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/anie.202105718es
dc.identifier.publicationfirstpage17410es
dc.identifier.publicationissue32es
dc.identifier.publicationlastpage17414es
dc.identifier.publicationtitleAngewandte Chemie International Editiones
dc.identifier.publicationvolume60es
dc.peerreviewedSIes
dc.description.projectMinisterio de Ciencia e Innovación (CTQ2016- 76393-P y PID2019-111396GB-I00)es
dc.description.projectJunta de Castilla y León (Subvenciones VA077U16 y VA244P20)es
dc.identifier.essn1521-3773es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones
dc.subject.unesco2210 Química Físicaes
dc.subject.unesco2303 Química Inorgánicaes


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