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dc.contributor.author | Kolesnikova, Lucie | |
dc.contributor.author | León Ona, Iker | |
dc.contributor.author | Alonso Alonso, Elena Rita | |
dc.contributor.author | Mata, Santiago | |
dc.contributor.author | Alonso Hernández, José Luis | |
dc.date.accessioned | 2022-01-10T09:25:51Z | |
dc.date.available | 2022-01-10T09:25:51Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Angewandte Chemie International Edition, 2021, vol. 60, n. 46, p. 24461-24466 | es |
dc.identifier.issn | 1433-7851 | es |
dc.identifier.uri | https://uvadoc.uva.es/handle/10324/51178 | |
dc.description | Producción Científica | es |
dc.description.abstract | The large amount of unstable species in the realm ofinterstellar chemistry drives an urgent need to develop efficientmethods for the in situ generations of molecules that enabletheir spectroscopic characterizations. Such laboratory experi-ments are fundamental to decode the molecular universe bymatching the interstellar and terrestrial spectra. We propose anapproach based on laser ablation of nonvolatile solid organicprecursors. The generated chemical species are cooled ina supersonic expansion and probed by high-resolution micro-wave spectroscopy. We present a proof of concept througha simultaneous formation of interstellar compounds and thefirst generation of aminocyanoacetylene using diaminomaleo-nitrile as a prototypical precursor. With this micro-laboratory,we open the door to generation of unsuspected species usingprecursors not typically accessible to traditional techniquessuch as electric discharge and pyrolysis. | es |
dc.format.mimetype | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Wiley | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject.classification | Chemical synthesis | es |
dc.subject.classification | Interstellar medium | es |
dc.subject.classification | Laser ablation | es |
dc.subject.classification | Molecular generation | es |
dc.subject.classification | Rotational spectroscopy | es |
dc.title | An innovative approach for the generation of species of the interstellar medium | es |
dc.type | info:eu-repo/semantics/article | es |
dc.rights.holder | © 2021 The Authors | es |
dc.identifier.doi | 10.1002/anie.202110325 | es |
dc.relation.publisherversion | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202110325 | es |
dc.identifier.publicationfirstpage | 24461 | es |
dc.identifier.publicationissue | 46 | es |
dc.identifier.publicationlastpage | 24466 | es |
dc.identifier.publicationtitle | Angewandte Chemie International Edition | es |
dc.identifier.publicationvolume | 60 | es |
dc.peerreviewed | SI | es |
dc.description.project | Czech Science Foundation (grant 19-25116Y) | es |
dc.description.project | Ministerio de Ciencia e Innovación (grants PID2019-111396GB-I00 and CTQ2016-76393-P) | es |
dc.description.project | Junta de Castilla y León (grants VA244P20 and VA077U16) | es |
dc.description.project | Consejo Europeo de Investigación (grant 610256) | es |
dc.identifier.essn | 1521-3773 | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.type.hasVersion | info:eu-repo/semantics/publishedVersion | es |
dc.subject.unesco | 23 Química | es |
dc.subject.unesco | 22 Física | es |
dc.subject.unesco | 2210 Química Física | es |
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