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dc.contributor.authorKolesnikova, Lucie
dc.contributor.authorLeón Ona, Iker 
dc.contributor.authorAlonso Alonso, Elena Rita 
dc.contributor.authorMata, Santiago
dc.contributor.authorAlonso Hernández, José Luis 
dc.date.accessioned2022-01-10T09:25:51Z
dc.date.available2022-01-10T09:25:51Z
dc.date.issued2021
dc.identifier.citationAngewandte Chemie International Edition, 2021, vol. 60, n. 46, p. 24461-24466es
dc.identifier.issn1433-7851es
dc.identifier.urihttps://uvadoc.uva.es/handle/10324/51178
dc.descriptionProducción Científicaes
dc.description.abstractThe large amount of unstable species in the realm ofinterstellar chemistry drives an urgent need to develop efficientmethods for the in situ generations of molecules that enabletheir spectroscopic characterizations. Such laboratory experi-ments are fundamental to decode the molecular universe bymatching the interstellar and terrestrial spectra. We propose anapproach based on laser ablation of nonvolatile solid organicprecursors. The generated chemical species are cooled ina supersonic expansion and probed by high-resolution micro-wave spectroscopy. We present a proof of concept througha simultaneous formation of interstellar compounds and thefirst generation of aminocyanoacetylene using diaminomaleo-nitrile as a prototypical precursor. With this micro-laboratory,we open the door to generation of unsuspected species usingprecursors not typically accessible to traditional techniquessuch as electric discharge and pyrolysis.es
dc.format.mimetypeapplication/pdfes
dc.language.isoenges
dc.publisherWileyes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subject.classificationChemical synthesises
dc.subject.classificationInterstellar mediumes
dc.subject.classificationLaser ablationes
dc.subject.classificationMolecular generationes
dc.subject.classificationRotational spectroscopyes
dc.titleAn innovative approach for the generation of species of the interstellar mediumes
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2021 The Authorses
dc.identifier.doi10.1002/anie.202110325es
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/anie.202110325es
dc.identifier.publicationfirstpage24461es
dc.identifier.publicationissue46es
dc.identifier.publicationlastpage24466es
dc.identifier.publicationtitleAngewandte Chemie International Editiones
dc.identifier.publicationvolume60es
dc.peerreviewedSIes
dc.description.projectCzech Science Foundation (grant 19-25116Y)es
dc.description.projectMinisterio de Ciencia e Innovación (grants PID2019-111396GB-I00 and CTQ2016-76393-P)es
dc.description.projectJunta de Castilla y León (grants VA244P20 and VA077U16)es
dc.description.projectConsejo Europeo de Investigación (grant 610256)es
dc.identifier.essn1521-3773es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones
dc.subject.unesco23 Químicaes
dc.subject.unesco22 Físicaes
dc.subject.unesco2210 Química Físicaes


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