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Título
Thermodynamic characterization of the (H2 + C3H8) system significant for the hydrogen economy: Experimental (p, ρ, T) determination and equation-of-state modelling
Autor
Año del Documento
2023
Editorial
Elsevier
Documento Fuente
International Journal of Hydrogen Energy Volume 48, Issue 23, 15 March 2023, Pages 8645-8667
Zusammenfassung
For the gradual introduction of hydrogen in the energy market, the study of the properties of mixtures of hydrogen with typical components of natural gas (NG) and liquefied petroleum gas (LPG) is of great importance. This work aims to provide accurate experimental (p, ρ, T) data for three hydrogen-propane mixtures with nominal compositions (amount of substance, mol/mol) of (0.95H2 + 0.05C3H8), (0.90H2 + 0.10C3H8), and (0.83H2 + 0.17C3H8), at temperatures of 250, 275, 300, 325, 350, and 375 K, and pressures up to 20 MPa. A single-sinker densimeter was used to determine the density of the mixtures. Experimental density data were compared to the densities calculated from two reference equations of state: the GERG-2008 and the AGA8-DC92. Relative deviations from the GERG-2008 EoS are systematically larger than those from the AGA8-DC92. They are within the ±0.5% band for the mixture with 5% of propane, but deviations are higher than 0.5% for the mixtures with 10% and 17% of propane, especially at low temperatures and high pressures. Finally, the sets of new experimental data have been processed by the application of two different statistical equations of state: the virial equation of state, through the second and third virial coefficients, B(T, x) and C(T, x), and the PC-SAFT equation of state.
Palabras Clave
Hydrogen; Propane; Binary mixtures; Single-sinker densimeter; Virial coefficients; Equation of state
ISSN
0360-3199
Revisión por pares
SI
Patrocinador
This work was funded by the European Metrology Programme for Innovation and Research (EMPIR, co-funded by the European Union's Horizon 2020 Research and Innovation Programme and EMPIR Participating States), Funder ID: 10.13039/100014132, Grant No. 19ENG03 MefHySto, the Ministerio de Economía, Industria y Competitividad, project ENE2017-88474-R, and the Junta de Castilla y León, project VA280P18.
Version del Editor
Idioma
spa
Tipo de versión
info:eu-repo/semantics/draft
Derechos
openAccess
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