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    Por favor, use este identificador para citar o enlazar este ítem:https://uvadoc.uva.es/handle/10324/65377

    Título
    Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
    Autor
    Ferrero, Sergio
    Barbero San Juan, HéctorAutoridad UVA Orcid
    Álvarez González, Celedonio ManuelAutoridad UVA Orcid
    Año del Documento
    2016
    Editorial
    MyJove Corp.
    Descripción
    Producción Científica
    Documento Fuente
    J. Vis. Exp. (115), e53954
    Abstract
    The main purpose of this video is to show 6 reaction steps of a convergent synthesis and prepare a complex molecule containing up to three nonplanar polyaromatic units, which are two corannulene moieties and a racemic hexahelicene linking them. The compound described in this work is a good host for fullerenes. Several common organic reactions, such as free-radical reactions, C-C coupling or click chemistry, are employed demonstrating the versatility of functionalization that this compound can accept. All of these reactions work for planar aromatic molecules. With subtle modifications, it is possible to achieve similar results for nonplanar polyaromatic compounds.
    Revisión por pares
    SI
    DOI
    10.3791/53954
    Patrocinador
    This work was funded by the Spanish Ministerio de Economìa y Competitividad (CTQ 2013-41067-P). H.B. acknowledge with thanks a MEC-FPI grant.
    Version del Editor
    https://app.jove.com/es/t/53954/preparation-of-a-corannulene--functionalized-hexahelicene-by-copperi--catalyzed-alkyne--azide-cycloaddition-of-nonplanar-polyaromatic-units
    Idioma
    eng
    URI
    https://uvadoc.uva.es/handle/10324/65377
    Tipo de versión
    info:eu-repo/semantics/publishedVersion
    Derechos
    openAccess
    Collections
    • MIOMeT - Artículos de revista [51]
    • CINQUIMA - Artículos de revista [162]
    • DEP63 - Artículos de revista [324]
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    Nombre:
    Alvarez - JoVE - Preparation of a Corannulene-functionalized Hexahelicene.pdf
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    Attribution-NonCommercial-NoDerivatives 4.0 InternacionalExcept where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 Internacional

    Universidad de Valladolid

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