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dc.contributor.authorSanz del Soto, Luis Felipe
dc.contributor.authorGonzález López, Juan Antonio Mariano 
dc.contributor.authorHevia de los Mozos, Luis Fernando 
dc.contributor.authorGarcía de la Fuente, Isaías Laudelino 
dc.contributor.authorCobos Hernández, José Carlos 
dc.date.accessioned2024-07-26T16:47:59Z
dc.date.available2024-07-26T16:47:59Z
dc.date.issued2023
dc.identifier.citationJournal of Solution Chemistry, 2024, 53, 160-181es
dc.identifier.issn0095-9782es
dc.identifier.urihttps://uvadoc.uva.es/handle/10324/69222
dc.description.abstractA differential scanning calorimetric technique has been used to obtain solid-liquid equilibrium temperatures for the mixtures naphthalene or biphenyl + 1-tetradecanol, or + 1-hexadecanol. All the systems show a simple eutectic point, whose final composition was determined by means of the Tamman’s plots using the needed values of the eutectic heat and of the heat of melting, which are also reported. DISQUAC interaction parameters for the OH/aromatic contacts in the selected systems are given. The present experimental SLE phase diagrams are similarly described by DISQUAC and UNIFAC (Dortmund) models. However, the comparison of DISQUAC and UNIFAC results for systems involving naphthalene and shorter 1-alkanols (methanol-1-octanol) reveals that the temperature dependence of the interaction parameters is more suitable in DISQUAC. The systems are also investigated in terms of the concentration-concentration structure factor. It is shown that the positive deviations from the Raoult’s law of the studied solutions become weaker when the homocoordination decreases.es
dc.format.mimetypeapplication/pdfes
dc.language.isospaes
dc.publisherSpringeres
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectTermodinámicaes
dc.titleSolid–Liquid Equilibria for the Binary Systems Naphthalene or Biphenyl + 1-Tetradecanol or + 1-Hexadecanoles
dc.typeinfo:eu-repo/semantics/articlees
dc.identifier.doi10.1007/s10953-023-01310-2es
dc.relation.publisherversionhttps://doi.org/10.1007/s10953-023-01310-2es
dc.identifier.publicationfirstpage160es
dc.identifier.publicationissue1es
dc.identifier.publicationlastpage181es
dc.identifier.publicationtitleJournal of Solution Chemistryes
dc.identifier.publicationvolume53es
dc.peerreviewedSIes
dc.description.projectProject VA100G19 (Apoyo a GIR), Castilla y Leon Regional Grantes
dc.identifier.essn1572-8927es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/submittedVersiones
dc.subject.unesco2213 Termodinámicaes


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