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Título
Viscosity of [C4mim][(CF3SO2)2N], [C4mim][N(CN)2], [C2mim][C2H5SO4] and [Aliquat][N(CN)2] in a wide temperature range. Measurement, correlation, and interpretation
Autor
Año del Documento
2021
Editorial
Elsevier
Descripción
Producción Científica
Documento Fuente
Journal of Molecular Liquids, Sep. 2021, vol. 337, p. 116482
Abstract
The viscosity of four in-house-made ionic liquids, 1-butyl-3-methyl-imidazolium bis(trifluoromethanesulfonylimide), ([C4mim][(CF3SO2)2N]), CAS RN 174899–83-3, 1-butyl-3-methyl-imidazolium dicyanamide, ([C4mim][N(CN)2]), CAS RN 448245–52-1, 1-ethyl-3-methyl-imidazolium ethylsulphate, ([C2mim][C2H5SO4]), CAS RN 342573–75-5 and methyltrialkyl(C8,C8,C10)ammonium dicyanamide [Aliquat][N(CN)2], CAS RN 63393–96-4, was measured in the temperature range 283.15 K − 373.15 K, at P = 0.1 MPa. Data obtained with an absolute relative uncertainty of Ur (η) = 0.02 was compared with available literature data for all ionic liquids, except for [Aliquat][N(CN)2], data herein presented for the first time. Both the Vogel-Tammann-Fulcher and IUPAC/IAPWS equations were applied to correlate the measured viscosity data as a function of temperature, the latter being more accurate. Values of η (298.15 K) are recommended for each ionic liquid studied. The viscosities of the different ionic liquids are discussed, considering their chemical structure differences.
Palabras Clave
Ionic liquids Viscosity 1-n-Butyl-3-methyl-imidazolium bis(trifluoromethanesulfonylimide) 1-n-Butyl-3-methyl-imidazolium dicyanamide 1-Ethyl-3-methyl-imidazolium ethylsulphate Methyltrialkyl(C8,C8,C10)ammonium dicyanamide Aliquat
ISSN
0167-7322
Revisión por pares
SI
Patrocinador
The authors are thankful for financial support from Fundação para a Ciência e a Tecnologia (Project PTDC/EQUFTT/102166/2008). This work was supported by the Associate Laboratory for Green Chemistry - LAQV which is financed by national funds from FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020) and by Centro de Química Estrutural – CQE, financed by national funds from Fundação para a Ciência e Tecnologia (UIDB/00100/2020 and UIDP/00100/2020).
Version del Editor
Propietario de los Derechos
Elsevier
Idioma
eng
Tipo de versión
info:eu-repo/semantics/publishedVersion
Derechos
restrictedAccess
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