2026-05-05T22:03:54Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/170262024-01-30T09:54:58Zcom_10324_1186com_10324_931com_10324_894com_10324_28542com_10324_952col_10324_1404col_10324_28543

Dramatic Mechanistic Switch in Sn/AuI Group Exchanges: Transmetalation vs. Oxidative Addition García Melchor, Max Casares González, Juan Ángel Espinet Rubio, Pablo Reacciones químicas The mechanism of Ph/X exchange in reactions involving SnPhnBu3 and [AuXL] complexes switches dramatically from the usual concerted mechanism involving Ar/X mixed bridges when X = Cl, to an unexpected oxidative addition/reductive elimination pathway via an AuIII intermediate when X = vinyl. 2016-05-30T11:26:19Z 2016-05-30T11:26:19Z 2016-05-30T11:26:19Z 2016 info:eu-repo/semantics/article Chem. Commun., 2016, 52, 4305-4308 1364-548X http://uvadoc.uva.es/handle/10324/17026 10.1039/C5CC10496C 4305 4308 Chemical Communications 52 eng http://dx.doi.org/10.1039/C5CC10496C info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Attribution 4.0 International Royal Society of Chemistry