2026-04-27T19:55:07Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/217092021-06-24T07:43:16Zcom_10324_1186com_10324_931com_10324_894com_10324_28542com_10324_952col_10324_1404col_10324_28543

Cordovilla, Carlos Bartolomé Albistegui, María del Camino Martínez de Ilarduya Martínez de Ilarduya, Jesús María Espinet Rubio, Pablo 2016-12-14T11:35:42Z 2016-12-14T11:35:42Z 2015 ACS Catalysis 2015, 5 (5), p. 3040–3053 2155-5435 http://uvadoc.uva.es/handle/10324/21709 10.1021/acscatal.5b00448 3040 5 3053 ACS Catalysis Producción Científica The first now named Stille reaction was published 38 years ago, and the last comprehensive revision of this catalysis was in 2004. Since then the knowledge of the different steps of the three possible (and sometimes competing) reaction pathways (cyclic, open, and ionic) has been almost completed by synergistic experimental and theoretical studies: the Stille reaction is perhaps the best characterized catalytic process if we consider the number of intermediates that have been detected. This review concentrates on the mechanistic new knowledge, and on important aspects as the revolution with the use of bulky phosphines, the bimetallic alternative of the Stille reaction, the enantioselectivity in Stille and palladium free Stille processes, the meaning of copper effect, or the possible approaches to make Stille coupling a greener process. Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. GR 169 and VA256U13) Ministerio de Economía, Industria y Competitividad (CTQ2013-48406-P) application/pdf eng American Chemical Society info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0/ Attribution-NonCommercial-NoDerivatives 4.0 International Stille cross-coupling The stille reaction, 38 years later info:eu-repo/semantics/article SI