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oai:uvadoc.uva.es:10324/217092021-06-24T07:43:16Zcom_10324_1186com_10324_931com_10324_894com_10324_28542com_10324_952col_10324_1404col_10324_28543

00925njm 22002777a 4500 dc Cordovilla, Carlos author Bartolomé Albistegui, María del Camino author Martínez de Ilarduya Martínez de Ilarduya, Jesús María author Espinet Rubio, Pablo author 2015 The first now named Stille reaction was published 38 years ago, and the last comprehensive revision of this catalysis was in 2004. Since then the knowledge of the different steps of the three possible (and sometimes competing) reaction pathways (cyclic, open, and ionic) has been almost completed by synergistic experimental and theoretical studies: the Stille reaction is perhaps the best characterized catalytic process if we consider the number of intermediates that have been detected. This review concentrates on the mechanistic new knowledge, and on important aspects as the revolution with the use of bulky phosphines, the bimetallic alternative of the Stille reaction, the enantioselectivity in Stille and palladium free Stille processes, the meaning of copper effect, or the possible approaches to make Stille coupling a greener process. ACS Catalysis 2015, 5 (5), p. 3040–3053 2155-5435 http://uvadoc.uva.es/handle/10324/21709 10.1021/acscatal.5b00448 3040 5 3053 ACS Catalysis Stille cross-coupling The stille reaction, 38 years later