2026-05-05T10:18:37Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/217282021-06-24T07:42:13Zcom_10324_1186com_10324_931com_10324_894com_10324_28542com_10324_952col_10324_1404col_10324_28543

Carrasco Fernández, Desiré Pérez Temprano, Mónica H. Casares González, Juan Ángel Espinet Rubio, Pablo 2014 Producción Científica Experiments on palladium catalyzed cross-coupling of [AuMe(PPh3)] with aryl iodides show that Ar–Ar homocoupling products are the main product or an abundant byproduct of the reaction. The percentage of cross-coupling product is higher for aryls with larger p Hammet parameter. The scrambling of organic groups via bimetallic intermediates explains the formation of these products. This scrambling can be observed and the activation energies partially quantified in some cases using as aryl C6Cl2F3, which is relatively reluctant to coupling. application/pdf http://uvadoc.uva.es/handle/10324/21728 eng American Chemical Society Catalyst Cross Alkyl-Aryl Versus Homo Aryl-Aryl Coupling in Pdcatalyzed Coupling of Alkyl-Gold(I) and Aryl-X (X = Halide) info:eu-repo/semantics/article TEXT UVaDOC. Repositorio Documental de la Universidad de Valladolid Hispana