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oai:uvadoc.uva.es:10324/217672025-02-20T09:32:27Zcom_10324_1186com_10324_931com_10324_894col_10324_1404

Lentijo, S. Exposito Fuertes, José Emilio Aullón, Gabriel Miguel García, Jesús Ángel Espinet Rubio, Pablo 2016-12-15T11:55:26Z 2016-12-15T11:55:26Z 2014 Dalton Transactions, 2014, 43, p. 10885-10897 1477-9226 http://uvadoc.uva.es/handle/10324/21767 10.1039/C4DT01016G Dalton Transactions The perylene derivatives 3-isocyanoperylene (Per–N≡C) (4a) and N-(2,5-di-tert-butylphenyl)- 9-isocyano-perylene-3,4-dicarboximide (PMI–N≡C) (4b) were prepared and used to synthesize gold complexes [AuX(CNR)] (X = C6F5 (5a,b), C6F4-OnBu-p (6b)). The reaction of 5b and 6b with HNEt2 led the carbene complexes [AuX{C(NEt2)(NHR)}] (7b, 8b), respectively. The molecular structure of complexes 7b, 8b have been determined by X-ray diffraction analysis showing intermolecular π–stacking of the perylene groups and C6F5 rings, and no Au···Au interactions. The derivative compounds [M(CO)5(CNR)] (M = Cr (9a,b), Mo (10a,b) or W (11a,b)) and trans-[Pd(CNR)2(C6F3Cl2)2] (12a,b) were also prepared. All complexes exhibit fluorescence associated to the perylene fragment with emission quantum yields, in solution at room temperature, in the range 0.05 – 0.93 and emission lifetimes ~ 4 ns. DFT calculations were performed of the absorption spectra of the ligands Per–N≡C and PMI–N≡C, and representative complexes [Au(C6F5)(CNR)], [Cr(CO)5(CNR)], showing a perylene-dominated intraligand π–π*emissive state, from the HOMO and LUMO orbitals of the perylene chromophore, but with significantly different absorption maxima by influence of the metal fragment, particularly significant in the Per–N≡C derivatives. eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0/ Attribution-NonCommercial-NoDerivatives 4.0 International Chemistry Highly fluorescent complexes with 3-isocyanoperylene and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene- 3,4-dicarboximide info:eu-repo/semantics/article