2026-04-28T19:29:07Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/234722025-03-04T10:09:29Zcom_10324_1186com_10324_931com_10324_894col_10324_1404

Furanosic forms of sugars: conformational equilibrium of methyl beta-D-ribofuranoside Écija, Patricia Uriarte, Iciar Spada, Lorenzo Davis, Benjamin Caminati, Walther Basterretxea, Francisco José Lesarri Gómez, Alberto Eugenio Cocinero, Emilio José Química The investigation of an isolated ribofuranose unit in the gas phase reveals the intrinsic conformational landscape of the biologically active sugar form.We report the rotational spectra of two conformers of methyl b-D-ribofuranoside in a supersonic jet expansion. Both conformers adopt a near twisted (3T2) ring conformation with the methoxy and hydroxymethyl substituents involved in various intramolecular hydrogen bonds. 2017-06-09T19:04:55Z 2017-06-09T19:04:55Z 2016 info:eu-repo/semantics/article ChemComm, 2016, 52, 6241 1359-7345 http://uvadoc.uva.es/handle/10324/23472 10.1039/c6cc01180b 6241 6244 Chemical Communications 52 spa info:eu-repo/semantics/openAccess Royal Society of Chemistry SI