2026-04-22T22:13:36Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/291612021-06-24T07:32:06Zcom_10324_1186com_10324_931com_10324_894com_10324_28542com_10324_952com_10324_28708com_10324_954col_10324_1404col_10324_28543col_10324_28709

Álvarez González, Celedonio Manuel Barbero San Juan, Héctor Ferrero, Sergio Miguel San José, Daniel 2018-03-20T13:03:18Z 2018-03-20T13:03:18Z 2016 Journal of Organic Chemistry, 2016, 81 (14), pp 6081–6086 0022-3263 http://uvadoc.uva.es/handle/10324/29161 10.1021/acs.joc.6b00454 Symmetric meso-tetraarylporphyrins bearing phenanthrene, pyrene, and corannulene moieties in meta positions have been synthesized in a straightforward procedure under microwave irradiation by quadruple Suzuki–Miyaura reactions. Their 1H NMR spectra showed the typical pattern of four atropisomers distributed according to their statistical ratio not properly separable due to their fast isomerization. Their ability to bind buckminsterfullerene has been tested with the whole mixture, and different behaviors have been found, α4 isomer corannulene-substituted porphyrins being the best hosts in the family. eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0/ Attribution-NonCommercial-NoDerivatives 4.0 International Synergistic Effect of Tetraaryl Porphyrins Containing Corannulene and Other Polycyclic Aromatic Fragments as Hosts for Fullerenes. Impact of C60 in a Statistically Distributed Mixture of Atropisomers info:eu-repo/semantics/article