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oai:uvadoc.uva.es:10324/436912023-06-08T10:34:56Zcom_10324_28708com_10324_954com_10324_894col_10324_28709

Hanf, Schirin Grell, Toni Waters, Jessica E. García Rodríguez, Raúl Hey-Hawkins, Evamarie Wright, Dominic Simon 2020-11-26T12:20:19Z 2020-11-26T12:20:19Z 2020 Chemical Communications, 2020, vol. 56, n. 57, p. 7893-7896 1359-7345 http://uvadoc.uva.es/handle/10324/43691 10.1039/D0CC02142C 7893 57 7896 Chemical Communications 56 1364-548X The reaction of the bis(methoxy)-2-pyridyl-phosphine (MeO)2P(2-py) (1) with [Ni(MeCN)6](BF4)2 leads to the unexpected single-step reduction of NiII and the formation of a tetrahedral nickel(0) complex [{(MeO)2P(2-py-H)}2{(MeO)2P(2-py)}2Ni](BF4)2 (2). The redox activity is probably induced by the decomposition of the tetrafluoroborate anion; NMR spectroscopic studies point towards a fluoride-assisted oxidation of the 2-pyridyl-phosphine ligand, with associated reduction of the metal. eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0/ © Royal Society of Chemistry Attribution-NonCommercial-NoDerivatives 4.0 Internacional Facile synthesis of a nickel(0) phosphine complex at ambient temperature info:eu-repo/semantics/article