2026-04-27T19:59:31Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/578952022-12-22T20:00:41Zcom_10324_28542com_10324_952com_10324_894col_10324_28543

Bardají Luna, Manuel 2022-12-22T09:44:06Z 2022-12-22T09:44:06Z 2014 Inorganics, 2014, vol. 2, n. 3, p. 433-454 2304-6740 https://uvadoc.uva.es/handle/10324/57895 10.3390/inorganics2030433 433 3 454 Inorganics 2 2304-6740 Producción Científica Since the first gold liquid crystal was described in 1986, much effort has been done to prepare new compounds bearing this property. The review deals with the last results obtained in this new century. Gold(I) has a strong affinity to give linear co-ordination and metal-metal interactions, which produce a rich supramolecular chemistry, and can promote the behavior as liquid crystal. Therefore, most liquid crystals are based on rod-like gold(I) compounds, while gold(III) liquid crystals are scarce. Calamitic and discotic mesogens have been reported, as well as chiral liquid crystals. Weak interactions such as H-bonds have also been used to obtain gold mesogens. Some of them exhibit additional properties, such as color, luminescence, and chirality. Luminescence has been reported, not only in the solid state or in solution, but also in the mesophase. This is relevant for applications in LEDs (Light Emitting Diodes), information storage, and sensors. Comisión Interministerial de Ciencia y Tecnología (Project CTQ2011–25137) Junta de Castilla y León (Proyecto VA302U13) application/pdf eng MDPI info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/3.0/ © 2014 The Author(s) Attribution 3.0 Unported Gold Liquid crystals Metallomesogens Isocyanide Calamitic Discotic Luminescence 22 Física 23 Química Gold liquid crystals in the XXI century info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion https://www.mdpi.com/2304-6740/2/3/433 SI