2026-05-05T21:28:37Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/636662023-12-22T10:06:12Zcom_10324_36327com_10324_954com_10324_894com_10324_1159com_10324_931col_10324_36329col_10324_1310

00925njm 22002777a 4500 dc Granja del Río, Alejandra author Cabria Álvaro, Iván author 2023 Metal-Organic Frameworks (MOFs) are a significant and promising category of solid that have garnered substantial attention for their potential in storing hydrogen and methane. Grand Canonical Monte Carlo (GCMC) simulations of the usable hydrogen and methane storage capacities of five DUT MOFs (Dresden University of Technology), based on tritopic ligands and copper, have been carried out at room temperature and pressures between 0.5 and 35 MPa. These DUT MOFs exhibit high usable hydrogen and methane storage capacities, comparable or higher than the storage capacities of the best classical MOFs and the best Cu-based MOFs. The usable methane gravimetric storage capacities at 35 MPa and room temperature of these DUTs reach the Department of Energy (DOE) methane gravimetric target and their usable volumetric capacities are close to the DOE methane volumetric target. International Journal of Hydrogen Energy, 2024 vol. 54, p. 665-677 0360-3199 https://uvadoc.uva.es/handle/10324/63666 10.1016/j.ijhydene.2023.11.258 International Journal of Hydrogen Energy Física Energy storage Exploring the hydrogen and methane storage capacities of novel DUT MOFs at room temperature: A Grand Canonical Monte Carlo simulation study