2026-05-05T20:25:39Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/745882025-09-17T06:36:53Zcom_10324_1186com_10324_931com_10324_894col_10324_1404

Calabrese ., Camilla Li, Weixing Prampolini, Giacomo Evangelisti, Luca Uriarte, Iciar Cacelli, Ivo Melandri, Sonia Cocinero, Emilio José 2025-01-29T14:21:21Z 2025-01-29T14:21:21Z 2019 Angew.Chem. Int.Ed. 2019, 58, 8437 – 8442 1433-7851 https://uvadoc.uva.es/handle/10324/74588 10.1002/anie.201902753 8437 25 8442 Angewandte Chemie International Edition 58 1521-3773 Rotational spectra of several difluoromethane–water adducts have been observed using two broadband chirpedpulse Fourier-transform microwave (CP-FTMW) spectrometers. The experimental structures of (CH2F2)···(H2O)2, (CH2F2)2···(H2O), (CH2F2)···(H2O)3, and (CH2F2)2···(H2O)2 were unambiguously identified with the aid of 18 isotopic substituted species. A subtle competition between hydrogen, halogen, and carbon bonds is observed and a detailed analysis was performed on the complex network of non-covalent interactions which stabilize each cluster. The study shows that the combination of stabilizing contact networks is able to reinforce the interaction strength through a cooperative effect, which can lead to large stable oligomers. application/pdf eng info:eu-repo/semantics/openAccess A General Treatment to Study Molecular Complexes Stabilized by Hydrogen‐, Halogen‐, and Carbon‐Bond Networks: Experiment and Theory of (CH2F2)n⋅⋅⋅(H2O)m info:eu-repo/semantics/article info:eu-repo/semantics/submittedVersion SI