2026-05-05T09:19:42Zhttps://uvadoc.uva.es/oai/request

oai:uvadoc.uva.es:10324/745882025-09-17T06:36:53Zcom_10324_1186com_10324_931com_10324_894col_10324_1404

Calabrese ., Camilla Li, Weixing Prampolini, Giacomo Evangelisti, Luca Uriarte, Iciar Cacelli, Ivo Melandri, Sonia Cocinero, Emilio José 2019 Rotational spectra of several difluoromethane–water adducts have been observed using two broadband chirpedpulse Fourier-transform microwave (CP-FTMW) spectrometers. The experimental structures of (CH2F2)···(H2O)2, (CH2F2)2···(H2O), (CH2F2)···(H2O)3, and (CH2F2)2···(H2O)2 were unambiguously identified with the aid of 18 isotopic substituted species. A subtle competition between hydrogen, halogen, and carbon bonds is observed and a detailed analysis was performed on the complex network of non-covalent interactions which stabilize each cluster. The study shows that the combination of stabilizing contact networks is able to reinforce the interaction strength through a cooperative effect, which can lead to large stable oligomers. application/pdf https://uvadoc.uva.es/handle/10324/74588 eng A General Treatment to Study Molecular Complexes Stabilized by Hydrogen‐, Halogen‐, and Carbon‐Bond Networks: Experiment and Theory of (CH2F2)n⋅⋅⋅(H2O)m info:eu-repo/semantics/article TEXT UVaDOC. Repositorio Documental de la Universidad de Valladolid Hispana